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The Linux Experiment - Making the Linux desktop accessible: no techno lingo, no command line voodoo, no super technical content.
Blender guru - Free and commercial tutorials
Level1Linux - The Level1Techs team is very knowledgeable while stilling being sociable as content creators. Wendell in-particular is often the feature figure of the Level1Linux content.
Khan Academy - Khan Academy offers online tools to help students learn about a variety of important school subjects. Tools include videos, practice exercises, and materials for instructors. Read more about Khan Academy.
Egee - Informative and entertaining videos about Open Source Software, Gaming, and other loosely related things.
Luke Smith - Everything you're looking for is here: http://lukesmith.xyz