Apple TV Tech Talks - Library of videos from Apple's dev team
The Twenty Minute VC (podcast) - Learn about venture capital, startup funding and the pitch
Random Casey - Get your daily dose of Casey Neistat. Watch a random episode
StartupTalks - A curated collection of startup related videos and podcasts
TED - The internet is great to provide us with our favorite TV shows free, early and watchable on demand.
Audify - What if you could learn a completely new concept in under 90 seconds?