Apple TV Tech Talks - Library of videos from Apple's dev team
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Random Casey - Get your daily dose of Casey Neistat. Watch a random episode
Spectacle V0 (previously Startup-Videos) - Showcasing the best startup videos
TED - The internet is great to provide us with our favorite TV shows free, early and watchable on demand.
StartupTalks - A curated collection of startup related videos and podcasts