Stylizer - A productivity-focused real-time CSS editor for serious web developers. Mac OS X and Windows.
Balthisar Cascade - Balthisar Cascade cascading style sheet editor will make learning and producing CSS easy!
EnjoyCSS - CSS generator for rich graphical styles without coding
CSSEdit - Design beautiful, innovative and fast-loading web sites… with a beautiful, innovative and fast app.
Topstyle - TopStyle contains powerful tools for building standards-compliant web sites.
BlueGriffon - An HTML editor based on Mozilla rendering engine.