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Inkscape - Inkscape is a free, open source professional vector graphics editor for Windows, Mac OS X and Linux.
Code2Flow - An easy solution to create product flows.
LaTeXDraw - LaTeXDraw is a graphical drawing editor for LaTeX.
DIagrams Through Ascii Art - Java command-line tool to convert ASCII diagrams to bitmaps.
Ipe - Ipe is a drawing editor for creating figures in PDF or (encapsulated) Postscript format.
Flowchart.js - Draw SVG flow charts from simple text representations of the diagrams.