draw.io - Online diagramming application
Dia - Dia is a GTK+ based diagram creation program for GNU/Linux, MacOS X, Unix, and Windows, and is released under the GPL license.
Automatic Organizational Chart Generator - Turn your Excel employee list into an Org Chart with Photos!
LibreOffice - Draw - Draw, LibreOffice, ODF, open standards, creative software, vector drawing
yEd - yEd is a free desktop application to quickly create, import, edit, and automatically arrange diagrams. It runs on Windows, Mac OS X, and Unix/Linux.
LucidChart - LucidChart is the missing link in online productivity suites. LucidChart allows users to create, collaborate on, and publish attractive flowcharts and other diagrams from a web browser.