Cold Turkey - Cold Turkey is a free productivity program that you can use to temporarily block distractions so that you can get your work done!
CurrentWare BrowseControl - BrowseControl web filtering software blocks websites based on URLs and categories. Policies can be customized for each user, department, or OU. Includes other features such as an app blocker, port filter, and download/upload blocker.
Stay Focused - More suitable with Google Chrome, this service enables you ensure you do not waste precious time on updating Facebook status or chatting with people.
Qustodio - Free parental control software. Monitor and track your child's online activity. Block dangerous sites and protect kids from online bullying.
Freedom.to - Freedom is a productivity hack that lets you block apps, websites or the entire Internet on iPhones, iPads, Windows and Mac computers.
NxFilter - Best performance. You don't want to slow down your network by installing a network security software. NxFilter is a light-weight DNS filter. It doesn't cause any latency issue in your network.