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Epic Pen - A windows tool for drawing over your desktop and applications
Inkscape - Inkscape is a free, open source professional vector graphics editor for Windows, Mac OS X and Linux.
Krita - Krita is a professional FREE and open source painting program. It is made by artists that want to seaffordable art tools for everyone. Concept art. texture and matte painters, illustrations and comics.
LaTeXDraw - LaTeXDraw is a graphical drawing editor for LaTeX.
PaintTool SAI - Learn to draw in different ways.
Ipe - Ipe is a drawing editor for creating figures in PDF or (encapsulated) Postscript format.