GnuCash - A personal and small-business financial-accounting software, licensed under GNU/GPL and available for Linux, Windows, Mac OS X, BSD, and Solaris.
Free Invoicing Software - Free Invoicing Software provides the facility of online billing.
Ledger-cli.org - Ledger is a powerful, double-entry accounting system that is accessed from the UNIX command-line.
Teamleader - CRM, invoicing & project planning in a single tool for SME's
Invoice Ninja - Invoice Ninja is a free, open-source solution for invoicing and billing customers.
Homemoney - HomeMoney: free service for planning of personal budget, family budget, small business budget. Possibility to reduce expenses and budget planning, accounting for small business.