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Trillian - Trillian is a decentralized and federated instant messaging platform that lets your whole company send private and group messages, keep tabs on what co-workers are doing, share files, and much more.
Copper Chat - Pay or get paid for private one-on-one video chats.
LimeChat - LimeChat is an IRC client for Windows, Mac OS X and iOS. Features
oorja - Your Dedicated Meeting Spaces Online — no installations
Adium - Adium is a free instant messaging application for Mac OS X that can connect to AIM, MSN, Jabber, Yahoo, and more.
Airmink - Secure and private 1-on-1 video, voice, chat, file sharing