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Diagrammix - Tool for efficiently building attractive diagrams.
Inkscape - Inkscape is a free, open source professional vector graphics editor for Windows, Mac OS X and Linux.
yEd - yEd is a free desktop application to quickly create, import, edit, and automatically arrange diagrams. It runs on Windows, Mac OS X, and Unix/Linux.
LaTeXDraw - LaTeXDraw is a graphical drawing editor for LaTeX.
ProcessMaker - ProcessMaker is an easy to use BPM and workflow software solution. It is used to design, automate, and deploy business processes of any kind.
Ipe - Ipe is a drawing editor for creating figures in PDF or (encapsulated) Postscript format.